Write mechanism of acid dehydration of ethanol to yield ethene.
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Explain the following with an example:
Unsymmetrical ether.

Unsymmetrical ether: Ethers in which the groups R and R’ are different are called unsymmetrical ethers.
Examples:



Williamson synthesis method is used for the preparation of symmetrical and unsymmetrical ethers.

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How are the following conversions carried out?
Propene → Propan-2-ol.

Propene is react with water in the presence of an acid as a catalyst, then propan-2-ol is obtained.

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Write mechanism of acid dehydration of ethanol to yield ethene.


Mechanism: The formation of ethylene and diethyl ether from ethanol and conc. H2SO4 may be explained as follows:

(a) Formation of ethene or ethylene:

Step 1. Due to the presence of two lone pairs of electrons on oxygen, alcohols act as weak bases. Therefore, they react with strong mineral acids (HCl, H2SO4 etc.) to form oxonium salts.




Step 2.
The presence of a positive charge on the highly electronegative oxygen atom weakens the C—O bond. Thus, the protonated ethanol readily eliminates a molecule of H
2O to form ethyl carbocation.



This step is slow and hence is the rate-determining step of the reaction.

Step 3. The ethyl carbocation formed in step 2 being a reactive chemical species, readily loses a proton to form the ethene molecule.





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Explain the following with an example:
Williamson ether synthesis.


Williamson’s synthesis: The reaction of alkyl halides with sodium alkoxide or sodium phenoxide to form ethers is called Williamson’s synthesis. For example,







This is one of the best methods for the preparation of both simple and mixed ethers.


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How are the following conversions carried out?
Benzyl chloride → Benzyl alcohol

Conversion of benzyl alcohol from benzyl chloride.

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